This is the way: An evidence based route to phytic-acid–based flame retardant poly (lactide acid)
Abstract
A systematic sequence of materials was investigated to develop phytic-acid (Phyt)–based flame retarded poly (lactide acid) (PLA), while factoring in molecular weight (MW), crystallinity and mechanical properties. Synergistic approaches were developed based on combinations with lignin and expandable graphite (EG), as well as by applying different Phyt salts of melamine (Mel), piperazine (Pip), and arginine (Arg). Compounds were twin screw extruded, injection molded, hot pressed and investigated with thermal analysis, size exclusion chromatography, infrared spectroscopy, tensile testing, limited oxygen index (LOI), UL 94, cone calorimeter, and scanning electron microscope. 16.7 wt.% flame retardant (FR) slightly enhances crystallization while MW remains unchanged in PLA Phyt Arg and PLA Phyt Mel. LOI was improved to 43.7 vol.% for PLA Phyt Arg, UL 94 V0 achieved for PLA Phyt Pip. Cone calorimeter results show total heat evolved reduced by 14 %, maximum average rate of heat emission 43 % lower, and peak heat release rate reduced by 50 % for PLA Phyt Mel. Phyt Mel combined with EG increased the char yield of PLA to 20 wt.% and 15.5 wt.% at 600 and 900 ◦C, respectively. Phyt is exploited to enhance char yield, stabilize the intumescent char, and lower the apparent effective heat of combustion. The combination of Phyt Mel and EG was proposed as an efficient FR for PLA via an evidence based developing route.
Mehr zum Titel
| Titel | This is the way: An evidence based route to phytic-acid–based flame retardant poly (lactide acid) |
|---|---|
| Medien | Conference Proceedings - 20th European Meeting on Fire Retardant Polymeric Materials (FRPM2025), Madrid Spanien |
| Verlag | Elsevier |
| Herausgeber | IMDEA Materials Institute, FRPM2025 - European Meeting on Fire Retardant Polymeric Materials |
| Heft | Volume 234, |
| Band | 2025 |
| ISSN | 0141-3910 |
| Verfasser | Jan Wagner, Mateusz Dudziak, Jana Falkenhagen, Daniel Rockel, Prof. Dr. Hans-Achim Reimann, Prof. Dr. rer. nat. habil. Bernhard Schartel |
| Seiten | 111242 |
| Veröffentlichungsdatum | 01.06.2025 |
| Projekttitel | TAKE |
| Zitation | Wagner, Jan; Dudziak, Mateusz; Falkenhagen, Jana; Rockel, Daniel; Reimann, Hans-Achim; Schartel, Bernhard (2025): This is the way: An evidence based route to phytic-acid–based flame retardant poly (lactide acid) . Conference Proceedings - 20th European Meeting on Fire Retardant Polymeric Materials (FRPM2025), Madrid Spanien 2025 (Volume 234,), 111242. DOI: 10.1016/j.polymdegradstab.2025.111242. |